|
Document Type |
: |
Article In Journal |
|
Document Title |
: |
2,13-Dibenzyl-5,16-diethyl-2,6,13,17-tetra-aza-tricyclo-[16.4.0.0 7,12]docosan-2-ium nitrate 2,13-Dibenzyl-5,16-diethyl-2,6,13,17-tetra-aza-tricyclo-[16.4.0.0 7,12]docosan-2-ium nitrate |
|
Subject |
: |
Chemistry |
|
Document Language |
: |
English |
|
Abstract |
: |
One of the tertiary amine atoms has been protonated in the title salt, C36H57N4+·NO3-. The four N atoms of the macrocycle are almost coplanar (r.m.s. deviation = 0.0053 Å), a result correlated with the formation of intra-molecular N - H⋯N and N - H⋯(N,N) hydrogen bonds. With respect to this plane, the benzyl groups lie to either side; a similar arrangement pertains for the cyclo-hexyl rings (each with a chair conformation). Helical supra-molecular chains are evident in the crystal, whereby alternating cations and anions are linked by C - H⋯O inter-actions. The chains are consolidated into supra-molecular arrays in the ab plane via C - H⋯π contacts involving both benzene rings. |
|
ISSN |
: |
1600-5368 |
|
Journal Name |
: |
Acta Crystallographica Section E: Structure Reports Online |
|
Volume |
: |
67 |
|
Issue Number |
: |
8 |
|
Publishing Year |
: |
1432 AH
2011 AD |
|
Article Type |
: |
Article |
|
Added Date |
: |
Saturday, December 10, 2011 |
|
Researchers
| J -H Choi | Choi, J -H | Researcher | Doctorate | |
| M A Subhan | Subhan, M A | Researcher | Doctorate | |
| Seik Weng Ng | Ng, Seik Weng | Researcher | Doctorate | seikweng@um.edu.my |
| E R T Tiekink | Tiekink, E R T | Researcher | Doctorate | edward.tiekink@gmail.com |
|